节点文献
六氯化铈三烷基鏻的合成
PREPARATION OF HEXACHLOROCERIUM-TRIALKYLPHOSPHONIUM
【摘要】 合成了三个新的(HPR3)2CeCl6络合物,其中R=C2H5,C3H7,C4H9。络合物经元素分析,红外和紫外光谱鉴定。用热重分析法研究了这些络合物的热分解行为,结果表明,它们于分解温度时,都首先失去一个氯原子。
【Abstract】 Three new complexes (HPR3)2CeCl6. where R=-C2H5-C3H7,-C4C9,were synthesized by means of adding PR3 into H2CeCl6 ethanol solutionunder bubbling of dry HCl. The complexes were identified by elementalanalysis, IR and visible spectra. In the thermogram of the complexes aninitial mass loss corresponding to the loss of a chlorine atom is observed.
- 【文献出处】 应用化学 ,Chinese Journal of Applied Chemistry , 编辑部邮箱 ,1984年04期
- 【被引频次】2
- 【下载频次】28