【摘要】 本文研究了Zn²⁺、Ni²⁺、Cu²⁺、Pb²⁺、Mg²⁺等金属卟啉单体及其二十四种聚合物的合成方法,在有关文献的基础上,给出了单体的较佳合成条件与精制方法。通过界面缩聚反应和相转移催化剂的应用使聚合反应在常温下顺利完成。并研究了金属络合对卟啉聚合反应活性的影响。更多还原

【Abstract】 IB this paper syntheses of Zn2+ Ni2+ Cu2+ Pb2+,Mg2+ metallopor-phyrims and their twenty-four polymers were studied.Better conditions for syntheses and effective purification methods of monomers were given.By means of interfacial condensation polymerization technology and phase transfer catolysts,we successfully accomplished the polymerization reactions at roon temperature.We also discussed the effect of metal-coordination on polymerization activity of porphyrins更多还原