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碘钟振荡反应中酸介质的研究

A Study of Acidic Mediums in Iodine Clock Cscillation Reaction

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【作者】 赵莲青;

【Author】 Zhao Lianqing (Department of Geology)

【机构】 西北大学地质系;

【摘要】 本文研究了碘钟振荡反应所用的酸种类,最近文献上用到的酸有硫酸、高氯酸、磷酸,此文用到的有硝酸,柠檬酸、酒石酸、乳酸、顺丁烯二酸,用到的有机化合物为丙二酸、乙酰丙酮、乙酰乙酸乙酯。从而扩大了碘钟振荡反应的体系范围,并提出氢离子催化的主要步骤。

【Abstract】 in this paper, the author studied the other kinds of acids used in the Iodine clock oscillation reaction such as nitric acid, citric acid, tartaric acid, lactic acid, maleic acid in stead of HCIO4 or H2SC4. As for the other organic substances which have been used, they are malonic acid, acetyl-acetone, ethyl acetylacetate. So the systems of B-R reaction are of very wide range, and the decisive step of hydrogen ion in catylytic reaction is suggested.

  • 【文献出处】 西北大学学报(自然科学版) ,Journal of Northwest University(Natural Science Edition) , 编辑部邮箱 ,1984年04期
  • 【被引频次】3
  • 【下载频次】426
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