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紫精类化合物及表面活性剂促进Pt/TiO2粉末体系光解水产氢

WATER PHOTOCLEAVAGE ON THE Pt/TlO2 POWDER,PROMOTED BY SEVERAL VOILOGENS AND THE SURFACTANT N-CPC

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【作者】 王复东宫瑞章施宗逵顾婉贞顾长立

【Author】 Wang Fu-dong Gong Rui-zhang Shi Zong-kui Gu Wan-zhen Gu Chang-Li (Dalin Institute of Chemical Physics,Academia Sinica)

【机构】 大连化学物理研究所大连化学物理研究所

【摘要】 本文报导了几种紫精类化合物作为TiO2半导体导带电子的扑获剂,在紫外光照射下促进Pt/Tio2粉末光解水产氢的行为及阳离子表面活性剂促进Pt/TiO2粉末光解水产氢的显著效果。

【Abstract】 In the paper.It is reported that several viologens and the surfactant N-CPC (Ncetyl pyridinium chloride) conld promote the photochemical cleavage of water on pt/ TiO2 powder-H2o sostem under illumination of UV light.The charaderistic colour(blue or violet) of the reduced viologens appeared when the TiO2-viologen system was illuminated.And the colour disappeared with H2-evolution when pt-cat was added to the above mentioned coloured suspensionThe amount of th evolved from pt/TiO2-system in the presence of N-CPC could be about 45 times higher than in the absence of it.The viologen was noted to be able to accept the excited electrons from TiO2 semiconducter.Those rusults have been discussed brifly.

  • 【文献出处】 太阳能学报 ,Acta Energiae Solaris Sinica , 编辑部邮箱 ,1984年02期
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