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中药路路通挥发油化学成分的鉴定

IDENTIFICATION OF THE CHEMICAL CONSTITUENTS OF THE VOLATILE OIL FROM CHINESE DRUG "LULUTONG", FRUIT OF LIQUIDAMBAR FORMOSANA HANCE

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【作者】 王志伟张兰年程务本郭济贤

【Author】 WANG ZHIWEI, ZHANG LANNIAN, CHBNG- WUBEN, CUO JIXIAN(Faculty of Pharmacy, Shanghai First Medical College, Shanghai)

【机构】 上海第一医学院药学系上海第一医学院药学系

【摘要】 对中药路路通(Fructus Liquidambaris)挥发油的化学成分进行了毛细管柱气相色谱-质谱鉴定,其重建总离子流(RIC)图显示54个峰。作者等鉴定了其中16种化学成分,即β-松油烯、β-蒎烯、柠檬烯、γ-松油烯、桃金娘醛、α-松油醇、反式-葛缕醇、百里香酚、香荆芥酚、胡椒烯、β-榄香烯、反式-β-金合欢烯、α-衣兰油烯、×-榄香烯、杜松烯和榄香醇。它们的化学结构式依次为Ⅰ~ⅩⅥ。

【Abstract】 The volatile oil was separated by steam distilation from the dried fruit of Liquidambar formosana Hance. The result of capillary GC analysis showed that the volatile oil contains at least 54 chemical constituents. By means of GO/MS combination, sixteen of them were identified as β-terpinene,β-pinene, limonene,γ-terpinene, myrtenal, α-terpineol, trans-carveol, thymol, carvacrol,copaene,β-elemene, trans-β-farnesene, α-munrolene, a-elemene, cadinene and elemol.These 16 constituents of the fruit of Liquidambar formosana Hanoe were reported for the first time.

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