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氯化锌对酰氯酰化N-苯基脲反应的催化作用
THE CATALYSIS OF ZINC CHLORIDE ON ACYLATION OF THE N-PHENYLUREA WITH ACYLHALIDE
【摘要】 ZnCl2对于酰氯直接酰化N-苯基脲的反应具有显著的催化作用。在ZnCl2存在下,酰基化产物N-酰基-N′-苯基脲衍生物的产率,与无催化剂的对照实验相比提高17—45%。多数酰氯在ZnCl2存在下生成N-酰基N′-苯基脲及其衍生物的产率可以达到70—80%。
【Abstract】 In this paper, the zinc chloride, as an effective catalyst for direct acylation of the N-phenylurea with acyl and aroyl chlorides, was studied. It was shown that the yields of the acylation reactions were 6—48% higher in the presence of ZnCl2 than those in the absence of ZnCl2. The yields of the acylation reactions with most acyl chlorides used in the presence of ZnCl2 could reach 70—80%.
- 【文献出处】 吉林大学自然科学学报 ,Journal of Jilin University , 编辑部邮箱 ,1984年04期
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