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季铵盐和中性磷(膦)酸酯对铕和钆的协同萃取分离
Separation of Eu and Gd by synergic extraction with quaternary ammonium salt and TBP or di-(1-methyl-heptyl) methyl phosphonate mixed extractants
【摘要】 <正> 1954年Cunninghame等首先发现用HTTA和TBP混合萃取镨和钕时有协同效应产生,因此人们对协同效应进行了大量的研究,发现了一些新的协同萃取体系。但把协同萃取体系实际应用于工业上稀土分离的却较少。主要原因是协同效应的结果往往使分离因素降低。Manning曾指出,协同效应不利于分离。我
【Abstract】 The synergic effect obviously increases the separation factor βEu/Gd when quaternary ammonium salt and di(1-methyl-heptyl) methyl phosphonate or TBP mixed extractants are used. The impurity Eu in Gd can be decreased to less than 6 ppm in a counter-current extraction system. The extractable species have been found to be RE(NO3)3·2 N 263·TBP and RE(NO3)3·N 263·2 P 350, where P 350 denotes di(1-methyl-heptyl)-methyl phosphonate.
- 【文献出处】 化学试剂 ,Chemical Reagents , 编辑部邮箱 ,1984年04期
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