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中子活化分析中钐与铀的相互干扰

Study of the interference between samarium and uranium in non-destructive neutron activation analysis

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【作者】 冯锡璋; 罗世华; 赵珍兰; 郭应焕; 黄忠祥; 杨瑞英; 江泳; 张元纪; 杨亦男;

【Author】 Feng Xizhang Luo Shihua Zhao Zhenlan Guo Yinghuan Huang Zhongxiang Yang Ruiying Jiang YongZhang Yuanji Yang Yinan (Institute of High Energy Physics, Acodemia Sinica)

【机构】 中国科学院高能物理研究所; 中国科学院高能物理研究所;

【摘要】 <正> 在钐与铀的不破坏中子活化分析中主要测量46.4小时153Sm的103.2keVγ的光峰和56.4小时259Np的277.6keVγ的光峰。但是,在239Np的衰变中,由于内转换还有较大的几率发射99.5与103.7keV的X射线(239Pu),它们与239Np的106.1keVγ严重干扰钐的测量。用SCORPIO/SPECTRAN软件包中的γ谱单峰分析程序分析由SCORPIO-3000计算机程控Ge(Li)γ谱仪测得的经中子活化的纯铀的γ(X)谱,在所得的结果中,

【Abstract】 In presenta paper, the interference between Sm and U in non-destructive neutron activation analysis has been studied. When the radioactivities of 153Sm and 239Np are close to each other, the 103.2keV photopeak of 153Sm and the 103.7keV photopeak of 239Np (239Pu) do not appear correctly if the single-peak analysis is used. It seriously interfered the accurate measurement of Sm. The overlapping-peak-analysis program designed by our laboratory can be used to obtain the mixture of these two peaks. We use the stripping method. i. e. after stripping the spectrum of pure uranium, the mixed γ spectrum of Sm and U go through the single-peak or overlapping-peak analysis. By this way, we can get the pure 103.2keV photopeak of 153Sm quite accurately. The stripping method can be used to strip the contributions of all the fission products of uranium. This also is the one of its advantages. The stripping method may have other applications in non-destructive neutron activation analysis.

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