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某些分子红外多光子解离的压力效应
The Pressure Effect in IR Multiphoton Dissociation of Some Polyatomic Molecules
【摘要】 根据不同的压力关系,指出分子的红外多光子解离(或反应)可分为两类:一炎遵循单分子解离规律,如SF6,Freon类等分子;另一类遵循双分子反应规律,如甲醛,甲醇,乙醇等分子。讨论了发生这种差别的原因。
【Abstract】 On the basis of various pressure dependences we point out that IR MPD (or reaction) can be classified into two kinds. One is unimolecular dissociation (such as SF6, Freon, etc.); another is bimolecular reaction (such as CH3OH, C2H5OH, CH3O. etc.). Reasons for this difference are discussed.
- 【文献出处】 中国科学技术大学学报 ,Journal of University of Science and Technology of China , 编辑部邮箱 ,1983年03期
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