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固氮酶铁钼辅因子模型化合物合成的研究——Ⅰ、光谱法研究合成方法的设计方案
Studies of the Synthesis of FeMo-co Modeling Compounds 1. Spectroscopic Studies of the Strategy in the Design of the Synthetic Method.
【摘要】 本文讨论了以K2MoS4,FeCl2,KOR（R=-CH2CH2OH或-CH3）为基本原料,合成固氮酶铁钼辅因子（FeMo-co）模型物合成方案的设计依据。系统地考察这种体系的电子吸收光谱和激光拉曼光谱特征及其随时间的变化。实验结果支持了所提出合成方案的设计依据。
【Abstract】 The strategy in the design of synthetic method for the synthesis of dicnbane-type modeling compounds of FeMo-co,with K2MoS4,FeCl2,KOR (R=-CH2CH2OH,or-CH3),and NaHS (or KHS) as the principal starting materials,has been discussed.A systematic study of the characteristic electronic absorption spectra and Laser Raman spectra of such systems,as well as the changes in spectral characteristics with time,has been made.The experimental results provide support for the strategy in the design of the synthetic method.
- 【文献出处】 厦门大学学报(自然科学版) ,Journal of Xiamen University(Natural Science) , 编辑部邮箱 ,1983年01期
- 【被引频次】3
- 【下载频次】59