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高压高温处理对A15Nb3(Al,Ge)结构成分及其超导性能的影响

EFFECTS OF HIGH PRESSURE-HIGH TEMPERATURE TREATMENT ON THE STRUCTURE COMPOSITION AND SUPERCONDUCTIVITY OF Nb3(Al, Ge)

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【作者】 赵有祥刘志毅王守证郭树权

【Author】 ZHAO YOU-XIANG LIU ZHI-YI WANG SHOU-ZHENG* Guo SHU-QUAN(Institute of Physics, Academia Sinica) Department of Physics, Peking University.

【机构】 中国科学院物理研究所北京大学物理系中国科学院物理研究所

【摘要】 在0—67kbar压力范围,对名义成分为Nb3(Al1-xGex)的合金(x=0.20,O.23,0.25;含有Al5+σ相)进行了热处理。X射线分析表明:1)随着压力的升高,Al5相的晶胞参数a0出现极大值;2)与Al5相结构成分密切相关的衍射峰(211),(210)的相对累积强度I211/I210随压力的变化与a0的变化类似;3)Al5相结构成分随压力向着富Nb的方向移动。低温测试结果表明:随着压力的升高,试样的超导转变温度降低,转变宽度出现极大值。

【Abstract】 Alloys of different nominal composition Nb3Al1-xGex (where x = 0.20, 0.23, 0.25 containing A15 + σ phases) have been heat-treated under high pressure up to 67kbar. With increasing treating pressure, 1) the lattice parameter of A15 phase as well as the I211/I210 of relative integral intensity of X-ray diffraction peak (211) and (210) of A15 phase having some concern with structure composition both exhibits a maximum, 2) the structure composition of A15 phase shifts toward the Nb-rich direction, 3) the superconducting transition temperature Tc decreases, while the width of superconducting transition temperature range shows a maximum. ......The results were discussed.

  • 【文献出处】 物理学报 ,Acta Physica Sinica , 编辑部邮箱 ,1983年01期
  • 【下载频次】67
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