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应用能量色散X射线荧光光谱法测定海洋沉积物Rb、Sr元素的方法研究

MEASUREMENT OF TRACE ELEMENTS Bb AND Sr IN OCEANIC SEDIMENT BY ENERGY-DISPERSIVE X-RAY FLUORESCENCE SPECTROMETRY

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【作者】 张秀莲何丽娟刘亚文马淑兰韩俊英

【Author】 Zhang Xiulian and He Lijuan (Institute of Oceanology, Academia Sinica) Liu Yawin, Ma Shulan and Han Junying (Institute of High Energy Physics, Academia Sinica)

【机构】 中国科学院海洋研究所中国科学院高能物理研究所中国科学院高能物理研究所

【摘要】 <正> 能量色散X射线荧光光谱法是一门新的应用技术。其优点是全自动化;分析快速,定性定量准确;并可同时进行多元素的分析。 应用能量色散X射线荧光分析,我们采用粉末压片厚样法对东海海洋沉积物中Rb、Sr元素进行了模拟测试,确定其基体的组成与地质矿产部研制的水系沉积物标准样GDs1-8

【Abstract】 In this paper, Energy-dispersive X-ray fluorescence Spectrometry and thick compressed powder sample slice were used for an analogous test to measure trace element Rb and Sr in oceanic sediment in the East China Sea. The matrix of the sample has been determined and the standard sample for analysing elements Rb and Sr has been prepared. The results of measurement are as follows: The measuring limits of concentration of elements Rb and Sr are 0.005% and 0.002% respectively. The relative error for each element is less than 10% and the relative deviation is less than 1.9%. This method provides some bases for resolving the distribution of elements Rb. Sr in oceanic sediment in continental shelf of the China Sea

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