【摘要】 <正> 前已报道四氟乙烯四聚体(全氟-3,4-甲基己烯-3)(1)、五聚体(全氟-3,4-二甲基-4-乙基己烯-2)(2)和脂肪烷氧以及脂肪胺的亲核反应.本文报道化合物1,2和芳香胺如苯胺、β-萘胺的反应.由于烯烃1、2双键处于分子中间,因而当亲核试剂进攻时,双键容易发生重排,生成的末端基烯烃更具反应性,故导致一取代、二取代、三取代以及环化降解等复杂产物.更多还原

【Abstract】 The reactions of tetrafluoroethylene tetramer（1）and pentamer（2） with aromatic amines, such as aniline and β-naphthylamine are reported.Compound 1 reacted with aniline in molar ratio 1:1 to give 3a and 4a as well as a small amount of 5a, in 1:2 molar ratio to give mainly 4a and 5a and a small amount of 3a and 6a, in 1:3 molar ratio to give 4a and to 5a.Compound 3a can be converted to 4a and 5a by further reaction with aniline in the presence of NEt₃ in ether, but 4a was not convered to 5a.Compound 4a reacted with aniline（1:1 molar ratio） in DMF in the presence of KF at 60℃ to give mainly 7a and a small amount of 8a. 4a reacted with aniline in DMF at 120～160℃ in the presence of KF to give a small amount of the interesting heterocycles 8a, 9a and 10a.Compound 2 similarly reacted with aniline in ether to give 11a, 12a, 13a and 14a, and with β-naphthylamine to give 11b, 13b, 15b as well as the condensed ring compound 16b.When compound 11a 12a, were reacted further with aniline in DMF-KF at 50～60℃ 13a and 15a were formed respectively, indicating that compounds 11a and 12a are the possible intermediates in the formation of both 13b and 15b.Compound 12a reacted with DMF at 120～140℃ to give the heterocycle 17a besides 7a and 15a. The structure of all new compounds were established through IR, ¹H and ¹⁹F NMR, MS and elemental analyses.更多还原