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CCl3F红外多光子解离及反应通道的分析

Analyses of the IR multiphoton dissociation process and the reaction channel of CCl3F

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【作者】 王培南万新农孙迭篪李富铭

【Author】 WANG PEINAN WAN XINNONG SUN DIECHI LI FUMING(Department of Physics, Fudan University)

【机构】 复旦大学物理系复旦大学物理系

【摘要】 用TEA CO2激光对CCl3F进行红外多光子解离.用染料激光诱发荧光和最终产物的红外光谱分析方法探测了解离中间产物Cl和CClF.解离的最终产物为CCl4、CCl2F2及C2Cl2F2的三个同分异构体.对解离过程和形成最终产物的可能反应通道进行了分析.

【Abstract】 A pulsed TEA CO2 lager was used for the IR photolysis of CCl3F. The dissociation fragments were detected by the methods of laser induced fluorescence and the IR analysis of the final products. The final products were CCl4, CCl2F2 and the three isomers of C2Cl2F2. The dissociation process of CCl3F and the possible reaction channels for the formation of the tinal products were discussed.

  • 【文献出处】 光学学报 ,Acta Optica Sinica , 编辑部邮箱 ,1983年09期
  • 【被引频次】1
  • 【下载频次】24
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