【摘要】 用TEA CO₂激光对CCl₃F进行红外多光子解离.用染料激光诱发荧光和最终产物的红外光谱分析方法探测了解离中间产物Cl和CClF.解离的最终产物为CCl₄、CCl₂F₂及C₂Cl₂F₂的三个同分异构体.对解离过程和形成最终产物的可能反应通道进行了分析.更多还原

【Abstract】 A pulsed TEA CO2 lager was used for the IR photolysis of CCl3F. The dissociation fragments were detected by the methods of laser induced fluorescence and the IR analysis of the final products. The final products were CCl4, CCl2F2 and the three isomers of C2Cl2F2. The dissociation process of CCl3F and the possible reaction channels for the formation of the tinal products were discussed.更多还原