节点文献

Cu（en）₂Ag（SCN）₃晶体的电子结构及其诠释

Electronic Structure of Cu（en）₂Ag（SCN）₃ and Its Interpretation

推荐 CAJ下载
PDF下载
不支持迅雷等下载工具，请取消加速工具后下载。

【Author】 Huang Debin(Department of Chemistry & Chemical Engineering, Fuzhou University)Huang Jinling(Fujian Institute of Research on the structure of Matter, Academia Sinica)Zhang Yongfeng and Li JianminDepartment of Morden Chemistry, China University of Science and Technology)

【机构】福州大学化学化工系；中国科学院福建物质结构研究所；中国科技大学近代化学系；

【摘要】根据X针线衍射实验对Cu（en）₂Ag（SCN）₃晶体的研究结果,利用非自由态铜（Ⅱ）的径向波函数估算了晶体中Cu（Ⅱ）的d轨道在C_2v对称性下的电子结构,结果与实测电子吸收光谱及EPR谱比较符合.更多还原

【Abstract】 Based upon X-ray structure determination, the crystal field terms of the square pyramid coordination of Cu（Ⅱ） in Cu（en）₂Ag（SCN）₃ have been estimated by using the wave function of the non-free state Cu（Ⅱ）. The results obtained are in good agreement with the experimental data of the crystalline electronic spectra and the EPR spectra.更多还原