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水溶液热力学研究——高温热力学量和E-pH图的电算方法
STUDIES OF THERMODYNAMICS OF AQUEOUS SOLUTIONS A Computerizing Method for Thermodynamic Data and E-pH Diagrams at High Temperatures
【摘要】 根据前文给出的 M—H2O 体系中物质优势分布方程式:sum from i=1 to k Max{DM1,DM2,DM3……DMk}(T-E-pH 空间)本文将着力于阐明 M—H2O 体系中物质热容(Cp)的统一表达形式,为 DT,M1的计算提供准备。依上式编制了求算高温热力学数量△G°f,Mi,T、E°T,Mi/Mj、pH°T,Mi/Mj和 E—pH 图的通用电算程序,并实施。
【Abstract】 The distribution equation of species in M-H2O systems appeared in the previouspaper by the author is: sum from i=1 to k Max{DM1,DM2,DM3,……DMk}(space of T-E-pH)According to the equation,the unified formula of heat capacity(Cp)of species inM-H2O systems is described in detail in this paper,and it will make preparation forDT·Mi calculation.Based on the equation a general source programme for thermodynamic data suchas △G°f,Mi·T,E°T,Mi/Mj,pH°T,Mi/Mjand E-pH diagrams at high temperatures has beencompiled and performed.
- 【文献出处】 有色金属 ,Nonferrous Metals , 编辑部邮箱 ,1982年02期
- 【被引频次】1
- 【下载频次】94