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冠醚类化合物在化学分析中的应用—18-冠-6—溴甲酚绿光度测定钾
Application of Crown Ether Compounds in Chemical Analysis——Determination of Potassium with 18-Crown-6- Bromocresol Green
【摘要】 <正> Takagi等人首先合成了生色冠醚—4′-苦胺基苯并-15-冠-5,经三氯甲烷萃取后可测定海水中的钾,经我们改进后可用于岩石和土壤中测定钾。Sumiyoshi等人用苯萃取18-冠-6-钾和溴甲酚绿用于血浆中钾的测定。但对测定的有关条件缺乏具
【Abstract】 in this paper, the conditions for the determination of potassium with 18-crown-6-bromocresol green by spectrophotometric method have been studied in detail. The LiOH-H2C2O< solution (pH3.7) was chosen as a masking reagent, then the selectivity of this method was increased. This procedure can be applied directly in the concentration range of 0-30 ug of potassium in water samples containing no ammonium ion.
- 【文献出处】 岩矿测试 ,Rock and Mineral Analysis , 编辑部邮箱 ,1982年02期
- 【被引频次】1
- 【下载频次】56