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四川某地含铜玄武岩氧化带中的硅孔雀石

CHRYSOCOLLA IN THE OXIDIZED ZONE FROM A COPPER BEARING—BASALT SOMWHERE IN SICHUAN PROVINCE

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【作者】 张如柏王型珍龚夏生王杏芬

【Author】 Zhang Rubo;Wang Xingzhen;Gong Xiasheng;Wang Xingfen Chengdu College of Geology 609 Geological Team, Sichuan the Ministry of Metallurgical Indusry

【机构】 成都地质学院成都地质学院川冶609地质队

【摘要】 <正> 硅孔雀石是铜矿床氧化带中常见的次生含水的铜硅酸盐矿物,现经研究表明,水在其中主要是以羟基形式存在,而呈中性水分子形式存在的水却居于次要地位,同时,后者的含量是不固定的。因此,该矿物的一般通式写为(Cu,Al)2 H2(Si2O5)(OH)4或H2Cu2(Si2O5)(OH)4·nH2O(M. Fleischer,1980)。应当还要提到的是,在矿物学文献中,还有水硅孔雀石(asperolite)一词,它(水硅孔雀石)是1966年由R.海

【Abstract】 A blue-green mineral was found in the oxidized zone from a copper-bearing basalt. Our Studies indicate that it is a water-bearing copper silicate mine- ral-chrysocolla. The chrysocolla occurs as irregular grain, from 0.5 to 2mm in diamter. It is green or bluish-green in colour, with luster on the fracture surface. No cleavage is observed. It has specific gravity of 3.013 and hardness of 2--2.5. Under the microscope, chrysocolla is translucent and it is from colourless to buish-green, weakly pleochroic. The mineral is biaxial crystal and negative, with Ng=1.592, Nm=1.588, Np=1.570, NN=0.022,(-)2v=60(obsd). The Chemical compositions of chrysocolla are SiO2 31.70, CuO 44.68, AL2O334,MgO 0.16,CaO 0.01,H2O+13.85, H2O-8.73, amounting to 100.47. The crystallo-chemical formula of chrysocolla calculated for cation=6 is: H1.6 Cu2.03 [(Si1.92Al0.092.01O5](OH)2. The strongest X-ray powdes lines are 4.452(3), 2.848(10), 2.491(4), 1.632 (8), 1.428 (8), 1.344(7). It is turnedinto tenorite and quartz+tenorite after heated to 850℃-960℃. Curves of IR and DTA of chrysocolla are also given in this paper.

  • 【文献出处】 矿物岩石 ,Journal of Mineralogy and Petrology , 编辑部邮箱 ,1982年04期
  • 【被引频次】7
  • 【下载频次】125
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