【摘要】 本文利用非自由态Mn(Ⅱ)、Co(Ⅱ)、Ni(Ⅱ)的径向波函数计算了Jφgenson的f-因子,计算结果与JφgenSOn的经验拟合值一致,使光谱化学序列和Jφgenson的f-因子得到了理论解释。更多还原

【Abstract】 Jφgenson’s f-factors have been calculated using the nonfree radial wave functions of Mn( Ⅱ), Co(Ⅱ)and Ni( Ⅱ ). The results calculated coincide with Jφgenson’s fitting values. Thus a theoretical interpretation for Jφgenson’s f-factors and spectrochemical series was suggested.更多还原