【摘要】 本文用同系共轭体系的光电子能谱得到的各级垂直电离势验证了同系能级线性规律,并对同系因子和同系能级因子随同系序数n和分子轨道序数k的变化关系与实验测得的分子轨道能级E(n,k)随n和k的变化关系作了比较。更多还原

【Abstract】 In the previous papers[4,5], the authors modified the Huckel MO theory and proposed the Linear Rule of the Homologous Energy Factor, which states that the energies E(n,k) of the molecular orbitals and the physical properties P of the homologs of different structural types are linear functions of the homologous energy factor X(n,k) :In the present investigation we have collected the vertical ionization data of many homotegous conjugated systems by using UV Photo electron speptroscppy and verified the proposed Rule with satisfactory result. Comparison with Tsiang Min-Chien’s Rule of Homologous Linearity was discussed in detail.更多还原