【摘要】 利用香叶基氯、6,7-环氧香叶基氯与巯基乙酸酯类的缩合反应,制得了10个新的萜烯硫醚类化合物:6,10-二甲基3-硫杂十一碳5,9-双烯酸酯(3a,b,c,d,e)和6,10-二甲基9,10-环氧3-硫杂十一碳5-烯酸酯(4a,b,c,d,e)。更多还原

【Abstract】 10 new terpenoid thioethers, such as 6, 10-dimethyl 3-thia-undcoa-5, 9-dienoic acid esters (3) and 6, 10-dimethyl 9, 10-epoxy-3-thia-5-undecenoio acid esters (4) were synthesized by condensation of thioglycolic acid esters with geranyl chloride (1) or 6, 7-epoxygeranyl chloride (2). Juvenile hormonal activities of the synthetio compounds to pupae of meal worm (Tenebrio molitor L.) were studied. It has been proved that the activities of the epoxy compounds (4) is higher than those of the olefinie compounds (3). Compounds of type 4 showed moderate morphogenetic effect to meal worm pupae at a dosage of 50μg/pupa.更多还原