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Eu3+在Y2O3-Bi2O3体系中发光性能的研究

INVESTIGATION OF THE LUMINESCENT PROPERTES OF Eu3+ IN Y2O3-Ri2O3 SYSTEM

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【作者】 张静筠许淑珍苏锵王庆元孙长英

【Author】 Zhang Jing-yun Xu Shu-zhen Su QiangWang Qing-yuan Sun Chang-ying (Changchun institute of Applied chemistry, Academia siniea)

【机构】 中国科学院长春应用化学研究所中国科学院长春应用化学研究所

【摘要】 <正> 一、引言 Y2O3:Eu3+磷光体中的Eu3+在6100(?)附近呈现很强的尖峰发射。这个磷光体虽然在阴极射线和短波紫外光(约2500(?))激发下是十分有效的,但是对于长波紫外光激发却很不灵敏。Datta於1967年报导在Y2O3:Eu3+磷光体中加入少量Bi3+,在3650(?)长波紫外光激发下可增强Eu3+在6100(?)的尖峰发射强度。

【Abstract】 In this peper the fluorescent spectra properties of Bi3+ and Eu3+in Y2O3-Bi2O3 system and the regularities of their variation are reported.The fluorescent spectraof Bi3+show an emission band at about 5100A under 3300A excitation. The emis-sion intensity enhances with the reduction of the Bi3+ content .Under 3500A excitation. the Eu3+ in Y2O3-Bi2O3 system gives a brigher red emission and the fluorescent intensities at about 6110A corresponding to 6D0-7F2 transition are stronger than that in Eu : Y2O3 system. In (Y1-X-0 143EuXBi0.142) 2O3 phosphor, the fluorescent intensities of Eu3+ enhance and that of Bi3+ decreases with the increaes of the Eu3+ concentration. No Eu3+ concentration quenching is observed until x=0.20 mol. These indicate that energy transfer from Bi3+ to Eu3+ occurs.

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