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4Cr25Ni20钢与1(1/4)Cr(1/2)Mo钢焊接融合区在500℃长期使用中脆性断裂的研究

The Brittle Cracks along the Welded Fusion Zone of 4Cr25Ni20 Stee1 and 1(1/4)Cr(1/2)Mo Stee1 Tubes after Long Exposure at 500℃

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【作者】 曹智本陆善炘

【Author】 Cao Zhiben and Lu Shanxin

【机构】 大连工学院机械系高温炉管科研组大连工学院机械系高温炉管科研组

【摘要】 本文利用着色探伤、低倍检验、金相分析、显微硬度及电子探针等方法,分析了某化肥厂一段转化炉炉管沿异种纲焊接融合区的爆裂事故。研究结果表明:4Cr25Ni20钢与1(1/4)Cr(1/2)Mo钢焊接融合区,在500℃左右, 近20000小时的运行中,1(1/4)Cr(1/2)Mo钢接近融合线部位,由于碳向焊缝扩散而发 生脱碳现象,沿异种钢的融合线折出薄壳状脆性碳化物相,融合区硬度升高,这是导 致融合区韧性下降,引起炉管沿融合线断裂的主要原因。

【Abstract】 Tubes of 1hc primary reformer furnace of an ammonia plant were exam- inated through dye penetrate; macro and micrometall-ographic; microhardness and micro-probe tests. The results ofs the examinations show that after 20000 hrs of operation at 500℃, the carbons of the 1(1/4)Cr(1/2)Mo Stecl diffused from heat affected zone to the welded fusion boundaryl the 1(1/4)Cr(1/2)Mo Stee1 side of the welded fusion boundary was decarburized and a thin shell-like brittle carbide was precipitated along the fusion boundary of the welding seam; the hardness of the welded fusion zone was incrcased. Theseare the reason of the brittle cracks along the welded fusion zone. Cracks started from the root of the welding seam.

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