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萨丽麝香的制备及其NMR
Preparation of Celestolide Musk and its NMR
【摘要】 <正> 天然麝香是一种优质香料,它的使用历史悠久、应用广泛。但它的来源有限,因此长期以来有关它的合成及其代用品得到许多人的研究。以往主要是试制大环麝香的类似化合物,近年来发现了茚满类具有良好的麝香气味,并引起了重视。萨丽麝香就是其中的一种,它的学名为1,1-二甲基-4-乙酰基-6-叔丁基茚满,具有工式的结构:
【Abstract】 1, l-dimethyl-6-tert-butylindane is made by reacting tert-butylbenzene and iso-prene in the presence of 93% sulfuric acid. After the 1, l-dimethyl-6-tert-buty-lindane react with acetyl chloride, compound I is obtained as colourless leaflets with very strong musk odour.Compound I is prepared by reacting 2,6-diisoprepyl phenol and isoprene, in the presence of 93% sulfuric acid. Ⅱ is a colourless crystalline material and has a strong and pleasant musk odour. I is suitable for use in perfumery. Ⅱ also exhibits pro-perties as an antioxidant.The structure of Ⅰ and Ⅱ was further confirmed by NMR.
- 【文献出处】 北京大学学报(自然科学版) ,Acta Scicentiarum Naturalum Universitis Pekinesis , 编辑部邮箱 ,1981年01期
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