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月光花叶中一种生理活性物质的分离及其结构测定
Isolation and Structure Determination of A Physiologically Active Substance from the Leaves of Calonyctlon acuelatum
【摘要】 月光花叶的乙醇粗提物,经中性氧化铝柱及硅胶柱层析,可得几个有生理活性的组份,其中活性最强的组份之一用稀乙醇重结晶,即得白色针状晶体。熔点161—162℃,[α]D21—60±2°(在EtOH中)。经定性分析,红外光谱、质谱及核磁共振谱等的分析结果表明:此结晶体为11-羟基十六烷酸乙酯的低聚糖甙。我们称之为月光花素甲(Calonyctin A),代号DC-2。 酯类糖甙(月光花素甲)经酸降解、分离,可得无色针状甙元,经鉴定为11-羟基十六烷酸乙酯;酯糖甙中的糖是由5克分子己醛糖所组成的。 月光花素甲是一种植物生长调节物质。
【Abstract】 A Physiologically active ingredient from leaves of evening-glory(Calonyction aculsatum(L.) House) has been isolated and purified by meansof column chromatography and recrystallization from dilute ethanol. One ofthe active ingredients is a colorless needle m.p. 161-162℃[α]D21-60±2°(in EtOH) .Preliminary characteristics of IR,MS,NMR spectra and functional-group tests show that the substance is an 1.1-O-pentuglycoside of ethyl jalapinolate,and we narned it Calonyctin A,or DC-2.The aglyconc is an ethyl H-hydroxyhexadecanatc, i.e. ethyl jalapinolate. Calonyctin A is Sound to be a plant growth regulator.
- 【文献出处】 厦门大学学报(自然科学版) ,Journal of Xiamen University(Natural Science) , 编辑部邮箱 ,1980年01期
- 【被引频次】8
- 【下载频次】36