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高聚物的二氧化碳激光裂解色谱研究 Ⅱ.丁二烯-丙烯腈共聚物组成的测定

STUDIES OF THE CARBON DIOXIDE LASER PYROLYSIS GAS CHROMATOGRAPHY ON POLYMERS Ⅱ. DETERMINATION OF THE COMPOSITION ON ACRYLONITRILE-BUTADIENE COPOLYMERS

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【作者】 舒敬值吏丽萍李昂张德武

【Author】 SHU JING-ZHI SHI LI-PING (Shanghia Institute of Organic Chemistry, Academia Sinica) LI ANG ZHANG DE-WU (Northwest Institute of Rubber Industrial Products, Xianyang)

【机构】 中国科学院上海有机化学研究所西北橡胶工业制品研究所西北橡胶工业制品研究所 咸阳咸阳

【摘要】 <正> 丁二烯-丙烯腈共聚物作为一种耐油性能优良的橡胶(丁腈橡胶),有十分广泛的用途。共聚物中腈基含量与其耐油、耐低温性能关系甚大,用途亦各有异。因此,在生产和使用中都须测定该共聚物中引进之丙烯腈含量。一般的元素分析定氮法(简称定氮法)周期较长,当共聚物

【Abstract】 Pyrolysis gas chromatography (PGC) equipped with carbon dioxide laser pyrolyzer was used for rapid determination of monomer component composition of acrylonitrilebutadiene copolymers. Relative ratio of peak height of the acrylonitrile to butadiene in the pyrograms exists good linear relationship with monomer component composition of the corresponding copolymers. Employing a standard curve, three samples of acrylonitrile-butadiene rubber with unknown composition were determined conveniently. The results show that the results from laser pyrolyses agreed quite well with those from chemical analyses.

  • 【文献出处】 化学学报 ,Acta Chimica Sinica , 编辑部邮箱 ,1980年03期
  • 【被引频次】4
  • 【下载频次】35
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