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ИЭМАИЛЬСКИЙ生色理論的初步研究

A Preliminary Study of Измаильский’s Theory of Color

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【作者】 朱永蔡士德路澄華

【Author】 R. Chu, S. D. Tsai, and C. H. Lu. Department of Chemistry, Nanking Uuiversity

【机构】 南京大学化学系有机化学教研组南京大学化学系有机化学教研组

【摘要】 <正> 有色化合物中,包括下列一种結構类型的化合物:其中B为吸电子基团,如—NO2,>C=O…等;K为共軛体系,如—C6H4—等;Q为連接二个共軛体系的基团,可以是使BK与AK共軛的—CH=N—,—N=N—也可以是不使BK与AK共軛的—CONH—,—CH2—NH—,—CH2CONH—…等;A为給电子基团,如—OCH3,—NH2等。發現当Q为—CONH—,

【Abstract】 A type of organic coloring compounds can be represented as:B—K—Q—K—A in which B and A are electro - acceptor (—NO2,>C=O,…) and electro-donor (—OCH3, —NH2…) respectively: K is a conjugated system (—C6H4 —, …) and Q is the connecting link between the two conjugated systems. discovered that even if B—K and K—A are insulated by such group as —NH—CH2—, —COH, or —CH2CONH—, the compounds are still colored and he explained that the color is due to intermolecular conjugation.The same type of compounds could be prepared from gallic acid: among which compounds Ⅱ Ⅳ and Ⅴ are unknowns. In comparing the color of the compound Ⅰ with Ⅱ or Ⅲ with Ⅳ and Ⅴ, we are convinced that the color of these compounds could be explained by theory.

  • 【文献出处】 南京大学学报(自然科学版) ,Journal of Nanjing University (Natural Sciences) , 编辑部邮箱 ,1957年02期
  • 【下载频次】17
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