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Gd-Co系非晶薄膜垂直于膜面的磁各向异性的起源

ORIGIN OF MAGNETIC ANISOTROPY IN AMORPHOUS Gd-Co BASED ALLOY FILMS AND IN CRYSTALLINE FeNi FILMS

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【作者】 金汉民陈慧男韩钟璠

【Author】 Jin Hanmin, Chen Huinan Han Zhongfan (Department of Physics)

【机构】 吉林大学物理系磁学教研室吉林大学物理系磁学教研室

【摘要】 本文认为,被网状非磁性介质(包括空隙)包围的磁性柱状组织的形状各向异性是Gd-Co系非晶膜磁各向异性的主要来源,由于Gd的易氧化和择优再溅射,使磁性柱表面层的磁性Gd含量低于柱内部,各向异性常数Ku可近似地表为: Ku=KaMa2+kbMb2+KabMaMb,其中Ma和Mb分别为柱内部和表面层构平均磁化强度,Ka,Kb和Kab是与膜结构的几何尺寸有关的系数。根据两种Ms(T)显著不同的偏压溅射Gd-Co-Mo膜的Ku(T)和Ms(T)的实验资料,用上式分别计算了它们的Ma(T)和Mb(T),结果表明,这两种膜的Ma(T)都呈现Gd含量多于平均成份2—4%的Gd-Co-Mo膜的Ms(T)特性,其中Ms(T)有低抵消点的膜还呈现出磁抵消点的特性,Mb(T)则呈现富Co膜的特性。这表明本文的模型基本正确,计算表明,这些膜的非磁性介质占20%以上,且柱的表面层厚度不很薄,用本文的模型还解释了Ku与膜的氧化程度等工艺因素的关系,另外,本文指出,用平均分子场分析所得的Co-Co和Co-Gd间的交换积分,Jco-co和Jco-Gd以及0°K下的Co的自旋值Sco(0)随对膜中非磁性介质的比体积的不同估计而明显变化;随这个比体积的增加,Jco-co值提高,Jco-cd和Sco(0)值降低。

【Abstract】 Perpendicular anisotropy(PA) in amorphous GdCo alloy films is thought to be produced by shape anisotropy based on columnar microstructure, The anisotropy constant Ku is approximately given by where Ka, Kb and Kab are the coefficients depending on geometrical factors of the columnar structure. Ma and Mb are average magnetization of inner part and magnetic Gb deficient surface layer of a column, respectively. Ma(T) and Mb(T) were Calculated for two different GdCoMo films, whose Ms(T) and Ku(T)have been known from experiments and the shape of their Ms(T) are quite different. The Ma(T) of both films correspond to the Ms(T) curves of GdCoMo films containing some more Gd contents than that of the specimens. Mb(T) of both films exhibit Ms(T) character of Co rich films. Some dependence of Ku on various deposition conditions are explained. By means of the mean-field analysis it is demonstrated that the calculated spin angular moment of Co Sco(O) at O K, exchange interaction energies JCo-Co and JCo-Gd are apparently dependent on the estimated volume fraction Vc of nonmagnetic network. With increasing Vc, Sco(O) and JCo-Gdmonotonically decrease, while JCo-Co increases. In crystalline FeNi films deposited at normal indidence in the presence of a magnetic field, the constant of the in-plane magnetic uniaxial anisotropy is given by where Kap is the part due to atomic pair ordering, (9λtλrE)/[4(l+μ)] arises from condition of fixed strain of magnetostriction and (14Mt2MT2b)/γ comes from anisotropy of the distances between neighbouring grains parallel to the film plane, which is the result of shape anisotropy of grains and isotropic distribution of grains in the plane. In the formula, t is the temperature of the substrate during deposition, T is the temperature at the time of measurement of K(?), EisYoug’s modulus,μ is Poisson’s ratio, b is the distance between neighbouring grains in the plane, γ is surface tensile of the grains, and λ is constant of magnetostriction. Mt2MT2 must be replaced by MT4 for small grain films. The calculated dependence of both composition and temperature ise in good agreement with experiments.

  • 【文献出处】 吉林大学自然科学学报 ,Journal of Jilin University , 编辑部邮箱 ,1979年04期
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