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“在盐的水溶液中非电解质活度系数的研究Ⅴ.无机盐对于邻硝基苯甲酸在水中溶度的影响”一文的增订

REVISION OF SOME CALCULATIONS IN "STUDIES OF ACTIVITY COEFFICIENTS OF NONELECTROLYTES IN AQUEOUS SALT SOLUTIONS. V. THE EFFECT OF SALTS ON THE SOLUBILITIES OF o-NITROBENZOIC ACID IN WATER"

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【作者】 杨旦黄子卿

【Author】 YANG TAN AND HUANG TZU-CHING(Research Laboratory of Physical and Colloid Chemistry, Peking University)

【机构】 北京大学物理化学和胶体化学研究室北京大学物理化学和胶体化学研究室

【摘要】 <正> I.在上题的文中(以下简称文献),作者遗漏了Bates等一文,因此根据下面的假设,计算邻硝基苯甲酸(HA)在高氯酸纳水溶液中的活度系数: γHA(N2CIO4)=γ0.01HBr(NaCIO4 (1) γHA(NaCIO4)=γ0.01HBr(NaCIO4)+γNaCIO4—γNaBr (2) 算出结果列于文献表2第6行(γ±即γHA(盐)的缩写),并根据这些γ±值,计算)y±,CH+,…,等值。由于Bates等已测定氯化氢在高氯酸钠水溶液中的活度系数,故只需假设γHA(NaCIO4)=

【Abstract】 In the article of the above title, we missed the paper of Bates and Urmston which contains the data of the activity coefficients of HCl in aqueous NaClO4 solution, γHCl[NaClO4], and calculated γ0.01HCl[NaClO4] (which was taken as γHA[NaClO4], HA=o-nitro-benzoic acid) by making certain assumptions. We now take their values of γ0.01HCl[NaClO4] as γHA[NaClO4] and recalculate the salting-out constant, k.At the time of publication of the article mentioned, lack of data of γHA[Me4NBr] and γMe4NBr in the literature forced us to assume γHA[MeNBr]=γ0.01HBr[KBr] for the calculation of k. The appearance of Lindenbaum and Boyd’s paper, this spring, which contains the data of the activity coefficients of tetraalkylammonium halides, enables us to calculate γ0.01HBr[MeBr] (which is taken as γHA[Me4NBr]) by using similar assumptions.The two new values of k’s, when placed among those of the other salts studied in[1], require no change in the salting-out order given.

  • 【文献出处】 化学学报 ,Acta Chimica Sinica , 编辑部邮箱 ,1965年02期
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