【摘要】 本文讨论从极谱半波电势求多核络合物的各级稳定常数的一般处理法。更多还原

【Abstract】 When metal ions Mn+ combines with liganda L -b to form a series of mono-and polynuclear complexes as follows:the various concentration equilibrium constants Kpq at constant ionic strength can be evaluated from the polarographic half wave potential measurements through the function Y0 as follows:where ks and (kc)0 are diffusion current constants and ΔE1/2 the difference of thehalf wave potentials of the simple and the complexed metal ions respectively.The method for evaluation of Kpq’s from Y0 has been described in detail.更多还原